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Issue 21, 2010
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Boron–nitrogen analogues of the fluorenyl anion

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Abstract

The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2′-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared to the fluorenyl anion.

Graphical abstract: Boron–nitrogen analogues of the fluorenyl anion

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Article information


Submitted
25 Feb 2010
Accepted
16 Apr 2010
First published
29 Apr 2010

Dalton Trans., 2010,39, 5084-5086
Article type
Communication

Boronnitrogen analogues of the fluorenyl anion

S. M. Mansell, N. C. Norman and C. A. Russell, Dalton Trans., 2010, 39, 5084
DOI: 10.1039/C0DT00028K

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