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Issue 5, 2010
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Kinetic and structural studies on ‘tethered’ Ru(ii) arene ketone reduction catalysts

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Abstract

A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using 1H NMR spectroscopy.

Graphical abstract: Kinetic and structural studies on ‘tethered’ Ru(ii) arene ketone reduction catalysts

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Article information


Submitted
04 Aug 2009
Accepted
27 Oct 2009
First published
01 Dec 2009

Dalton Trans., 2010,39, 1395-1402
Article type
Paper

Kinetic and structural studies on ‘tethered’ Ru(II) arene ketone reduction catalysts

F. K. (. Cheung, A. J. Clarke, G. J. Clarkson, D. J. Fox, M. A. Graham, C. Lin, A. L. Crivillé and M. Wills, Dalton Trans., 2010, 39, 1395
DOI: 10.1039/B915932K

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