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Issue 33, 2010
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Clusters for alkyne-azide click reactions

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The clusters Ti6O4(OPr)8(OOC(CH2)2C[triple bond, length as m-dash]CH)8 and [Zr6O4(OH)4(OOC(CH2)3C[triple bond, length as m-dash]CH)12]2 with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic–organic hybrid materials by alkyne-azide click reactions.

Graphical abstract: Clusters for alkyne-azide click reactions

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The article was received on 08 Jun 2010, accepted on 12 Jul 2010 and first published on 26 Jul 2010

Article type: Communication
DOI: 10.1039/C0DT00618A
Dalton Trans., 2010,39, 7640-7644

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    Clusters for alkyne-azide click reactions

    P. Heinz, M. Puchberger, M. Bendova, S. O. Baumann and U. Schubert, Dalton Trans., 2010, 39, 7640
    DOI: 10.1039/C0DT00618A

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