Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes

Joon Soo Han; Takahiro Sasamori; Yoshiyuki Mizuhata; Norihiro Tokitoh

doi:10.1039/C0DT00115E

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Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes†

Joon Soo Han,‡^a Takahiro Sasamori,^a Yoshiyuki Mizuhata^a and Norihiro Tokitoh*^a

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* Corresponding authors

^a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, Japan
E-mail: tokitoh@boc.kuicr.kyoto-u.ac.jp
Fax: +82 774 38 3209
Tel: +81 774 38 3200

Abstract

The reactivity of a diaryl-substituted disilyne, Ar–Si [triple bond, length as m-dash] Si–Ar, with alkynes was examined. Reaction of the disilyne with acetylene yielded a 1,2-disilabenzene as the sole product.

This article is part of the themed collection: New horizon of organosilicon chemistry

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DOI: https://doi.org/10.1039/C0DT00115E
Article type: Communication
Submitted: 11 Mar 2010
Accepted: 09 Jun 2010
First published: 22 Jun 2010

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Dalton Trans., 2010,39, 9238-9240

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Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes

J. S. Han, T. Sasamori, Y. Mizuhata and N. Tokitoh, Dalton Trans., 2010, 39, 9238 DOI: 10.1039/C0DT00115E

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Dalton Transactions

Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes†

Abstract

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Article information

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Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes

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