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Issue 9, 2010
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Self-assembly of silver(i) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole “click” ligands

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Abstract

Readily synthesised mono- and di- 1,4-substituted-1,2,3-triazole “click” ligands are shown to self-assemble into discrete metallocyclic architectures with Ag(I) ions. The silver metallomacrocycles are stable in solution and the solid state and have been fully characterised by elemental analysis, HR-ESMS, IR, 1H and 13C NMR and in three cases the structures were confirmed by X-ray crystallography.

Graphical abstract: Self-assembly of silver(i) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole “click” ligands

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Supplementary files

Article information


Submitted
05 Nov 2009
Accepted
06 Jan 2010
First published
19 Jan 2010

Dalton Trans., 2010,39, 2371-2378
Article type
Paper

Self-assembly of silver(I) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole “click” ligands

M. L. Gower and J. D. Crowley, Dalton Trans., 2010, 39, 2371
DOI: 10.1039/B923211G

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