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Issue 5, 2010
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Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

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Abstract

Catalytic hydroamination reactions involving the addition of carboxamides (X = CO), carbamates (X = CO2) and sulfonamides (X = SO2) to unactivated C[double bond, length as m-dash]C bonds are briefly reviewed. Development in this field of catalytic research is briefly charted, followed by a discussion of possible mechanisms, including arguments to support the operation of both metal and Brønsted acid catalysis in these systems. Future developments in the area are summarised.

Graphical abstract: Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

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Publication details

The article was received on 11 Sep 2009, accepted on 29 Oct 2009 and first published on 07 Dec 2009


Article type: Frontier
DOI: 10.1039/B918970J
Dalton Trans., 2010,39, 1171-1175

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    Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

    J. G. Taylor, L. A. Adrio and K. K. (. Hii, Dalton Trans., 2010, 39, 1171
    DOI: 10.1039/B918970J

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