Issue 39, 2010
From the journal:

Physical Chemistry Chemical Physics

Infrared spectroscopic study of the amidation reaction of aminophenyl modified Au surfaces and p-nitrobenzoic acid as model system

Xin Zhang,a   Guoguang Sun,b   Karsten Hinrichs,b   Silvia Janietzc  and  Joerg Rappich*a  

* Corresponding authors

a Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Institut für Si-Photovoltaik, Kekuléstr. 5, 12489 Berlin, Germany
E-mail: rappich@helmholtz-berlin.de
Fax: +49 30806241333
Tel: +49 30806241386

b Leibniz-Institut für Analytische Wissenschaften-ISAS-e.V., Department Berlin, Albert-Einstein-Str. 9, 12489 Berlin, Germany
E-mail: karsten.hinrichs@isas.de
Fax: +49 3063923544
Tel: +49 3063923541

c Fraunhofer-Institut für Angewandte Polymerforschung, Geiselbergstraße 69, 14476 Potsdam-Golm, Germany
E-mail: silvia.janietz@iap.fraunhofer.de
Fax: +49 3315683910
Tel: +49 3315681208

Abstract

We have investigated the fundamental amidation reaction by a model system consisting of an electrochemically functionalised Au surface by aminophenyl and 4-nitrobenzoic acid activated by EEDQ. The development of the NO2 related stretching vibrations with time reveals that the amidation process is very slow at Au surfaces and is completed after about 2 days.

Graphical abstract: Infrared spectroscopic study of the amidation reaction of aminophenyl modified Au surfaces and p-nitrobenzoic acid as model system

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Article information

DOI
https://doi.org/10.1039/C0CP00058B
Article type
Communication
Submitted
29 Mar 2010
Accepted
05 Aug 2010
First published
25 Aug 2010

Phys. Chem. Chem. Phys., 2010,12, 12427-12429

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Infrared spectroscopic study of the amidation reaction of aminophenyl modified Au surfaces and p-nitrobenzoic acid as model system

X. Zhang, G. Sun, K. Hinrichs, S. Janietz and J. Rappich, Phys. Chem. Chem. Phys., 2010, 12, 12427 DOI: 10.1039/C0CP00058B

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