Issue 35, 2010
From the journal:

Physical Chemistry Chemical Physics

Hydrogen spillover measurements of unbridged and bridged metal–organic frameworks—revisited

Renato Campesi,ab   Fermín Cuevas,b   Michel Latrocheb  and  Michael Hirscher*a  

* Corresponding authors

a Chimie Métallurgique des Terres Rares, ICMPE, UMR7182, CNRS, 2 rue Henri Dunant, 94320 Thiais Cedex, France

b Max-Planck-Institut für Metallforschung, Heisenbergstrasse 3, D-70569 Stuttgart, Germany
E-mail: hirscher@mf.mpg.de
Fax: +49 711 6891952
Tel: +49 711 6891808

Abstract

The room-temperature hydrogen uptake of unbridged and bridged composites formed by a physical mixture of either (IRMOF-1)–(AC/Pt catalyst) or (IRMOF-1)–(AC/Pt catalyst) and sucrose, respectively, has been carefully measured and compared with previous results reported by Li and Yang. Contrary to their findings, no enhanced hydrogen uptake in the composite was found as compared to the initial IRMOF-1. If any spillover effect occurred it was below the detection limit.

Graphical abstract: Hydrogen spillover measurements of unbridged and bridged metal–organic frameworks—revisited

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Article information

DOI
https://doi.org/10.1039/C0CP00037J
Article type
Paper
Submitted
26 Mar 2010
Accepted
08 Jun 2010
First published
03 Jul 2010

Phys. Chem. Chem. Phys., 2010,12, 10457-10459

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Hydrogen spillover measurements of unbridged and bridged metal–organic frameworks—revisited

R. Campesi, F. Cuevas, M. Latroche and M. Hirscher, Phys. Chem. Chem. Phys., 2010, 12, 10457 DOI: 10.1039/C0CP00037J

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