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Interaction of apohemoprotein with a covalently immobilized heme moiety onto a gold nanoparticle surface resulted in supramolecular hemoproteingold nanoparticle conjugates. The addition of an apohemoprotein dimer further led to a densely-packed hemoproteingold nanoparticle assembly, which was visualized by TEM and AFM measurements.

Graphical abstract: Supramolecular hemoprotein–gold nanoparticle conjugates

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