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Issue 41, 2010
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Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

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Abstract

DC magnetic studies on new ‘star’ clusters of formula [Mn3Ln(acac)6(tea)2][Mn(acac)3] (Ln = Gd (1) and Dy (2)) and [Fe3Ln(acac)6(tea)2] (Ln = Gd (3) and Dy (4)) show that all cases display weak coupling, with compounds 3 and 4 displaying ferromagnetic JLnFe coupling, 3 having a S = 11 ground state.

Graphical abstract: Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

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Article information


Submitted
18 Jul 2010
Accepted
18 Aug 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7787-7789
Article type
Communication

Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

N. F. Chilton, S. K. Langley, B. Moubaraki and K. S. Murray, Chem. Commun., 2010, 46, 7787
DOI: 10.1039/C0CC02642E

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