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Issue 32, 2010
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Stereocontrolled synthesis of quaternary cyclopropyl esters

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Abstract

Treatment of a variety of enantiopure terminal epoxides with the anion of a range of 2-substituted triethylphosphonoacetates leads to an array of quaternary cyclopropyl esters with high yield and diastereocontrol.

Graphical abstract: Stereocontrolled synthesis of quaternary cyclopropyl esters

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Supplementary files

Article information


Submitted
10 May 2010
Accepted
22 Jun 2010
First published
13 Jul 2010

Chem. Commun., 2010,46, 5867-5869
Article type
Communication

Stereocontrolled synthesis of quaternary cyclopropyl esters

C. D. Bray and F. Minicone, Chem. Commun., 2010, 46, 5867
DOI: 10.1039/C0CC01333A

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