Issue 15, 2010
From the journal:

Chemical Communications

Kinetic resolution of trans-cycloalkane-1,2-diols via Steglich esterification†

Radim Hrdina,‡a   Christian E. Müller‡a  and  Peter R. Schreiner*a  

* Corresponding authors

a Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, 35392 Giessen, Germany
E-mail: prs@org.chemie.uni-giessen.de
Fax: 0641/99 34309
Tel: 0641/99 34300

Abstract

We describe the efficient and highly enantioselective kinetic resolution of trans-cycloalkane-1,2-diols utilizing an enantioselective Steglich reaction with a variety of carboxylic acids that form the corresponding anhydrides in situ.

Graphical abstract: Kinetic resolution of trans-cycloalkane-1,2-diols via Steglich esterification

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Article information

DOI
https://doi.org/10.1039/C001075H
Article type
Communication
Submitted
18 Jan 2010
Accepted
01 Feb 2010
First published
25 Feb 2010

Chem. Commun., 2010,46, 2689-2690

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Kinetic resolution of trans-cycloalkane-1,2-diols via Steglich esterification

R. Hrdina, C. E. Müller and P. R. Schreiner, Chem. Commun., 2010, 46, 2689 DOI: 10.1039/C001075H

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