Exploring the limits of 73Ge solid-state NMR spectroscopy at ultrahigh magnetic field

Andre Sutrisno; Margaret A. Hanson; Paul A. Rupar; Victor V. Terskikh; Kim M. Baines; Yining Huang

doi:10.1039/B926071D

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Exploring the limits of ⁷³Gesolid-state NMR spectroscopy at ultrahigh magnetic field†

Andre Sutrisno,^a Margaret A. Hanson,^a Paul A. Rupar,^a Victor V. Terskikh,^b Kim M. Baines*^a and Yining Huang*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Western Ontario, London, Ontario, Canada
E-mail: yhuang@uwo.ca, kbaines2@uwo.ca
Tel: 519 661 2111 x86384

^b Steacie Institute for Molecular Sciences, National Research Council, Ottawa, Ontario, Canada
E-mail: Victor.Terskikh@nrc-cnrc.gc.ca
Fax: 613 990 1555
Tel: 613 998 5552

Abstract

The ultrahigh field natural abundance ⁷³Ge solid-state wide-line NMR study of germanium dichloride complexed with 1,4-dioxane and tetraphenylgermane yields the largest ⁷³Ge quadrupolar coupling constant determined by NMR spectroscopy to date and the first direct observation of ⁷³Ge chemical shift anisotropy.

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Supplementary files

Experimental details, ⁷³Ge static piecewise-frequency stepped QCPMG NMR spectra of GeCl ₂·dioxane, ⁷³Ge MAS and static echo NMR spectra of GePh ₄, calculated ⁷³Ge NMR parameters using CASTEP PDF (1412K)

Article information

DOI: https://doi.org/10.1039/B926071D
Article type: Communication
Submitted: 10 Dec 2009
Accepted: 19 Feb 2010
First published: 20 Mar 2010

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Chem. Commun., 2010,46, 2817-2819

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Exploring the limits of ⁷³Ge solid-state NMR spectroscopy at ultrahigh magnetic field

A. Sutrisno, M. A. Hanson, P. A. Rupar, V. V. Terskikh, K. M. Baines and Y. Huang, Chem. Commun., 2010, 46, 2817 DOI: 10.1039/B926071D

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