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Issue 15, 2010
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Tin–lanthanoid donor–acceptor bonds

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Abstract

Reactions of a lithium tris(2-pyridyl)stannate with lanthanoid metal organic compounds resulted in the formation of novel donor–acceptor complexes, containing a low valent tinlanthanoid bond; DFT calculations reveal that this bond exhibits some covalent character.

Graphical abstract: Tin–lanthanoid donor–acceptor bonds

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Article information


Submitted
26 Nov 2009
Accepted
09 Feb 2010
First published
24 Feb 2010

Chem. Commun., 2010,46, 2638-2640
Article type
Communication

Tinlanthanoid donor–acceptor bonds

K. Zeckert, S. Zahn and B. Kirchner, Chem. Commun., 2010, 46, 2638 DOI: 10.1039/B924967B

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