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Issue 6, 2010
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Platinum substituted boroles

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The unprecedented 1-metalloborole [(Cy3P)2Pt(Cl)(BC4Ph4)] (1) and its T-shaped cationic derivative (2) were successfully prepared and structurally characterized. Fine-tuning the electronics of the boron-bound metal complex leads to a significant change in the lowest electronic transition energy of the 1-metalloboroles.

Graphical abstract: Platinum substituted boroles

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The article was received on 12 Nov 2009, accepted on 15 Dec 2009 and first published on 11 Jan 2010

Article type: Communication
DOI: 10.1039/B923652J
Chem. Commun., 2010,46, 916-918

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    Platinum substituted boroles

    H. Braunschweig, C. Chiu, K. Radacki and P. Brenner, Chem. Commun., 2010, 46, 916
    DOI: 10.1039/B923652J

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