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Issue 1, 2010
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Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

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Abstract

An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine β-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

Graphical abstract: Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

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Article information


Submitted
11 Aug 2009
Accepted
08 Oct 2009
First published
02 Nov 2009

Chem. Commun., 2010,46, 100-102
Article type
Communication

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

J. Hopewell, P. Jankowski, C. L. McMullin, A. G. Orpen and P. G. Pringle, Chem. Commun., 2010, 46, 100
DOI: 10.1039/B916359J

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