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Issue 12, 2010

Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(iv)

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Abstract

Hydrolysis of the trifluoroethenyl titanium complexes 1a and b yields the hydroxo complexes 2 which can be deprotonated forming the sodium salt of the anionic oxo complex 4. 4a is one of the rare examples of monomeric organometallic anionic oxo complexes.

Graphical abstract: Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(iv)

Supplementary files

Article information


Submitted
08 Dec 2009
Accepted
27 Jan 2010
First published
15 Feb 2010

Chem. Commun., 2010,46, 2118-2120
Article type
Communication

Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(IV)

R. Kickbusch and D. Lentz, Chem. Commun., 2010, 46, 2118 DOI: 10.1039/B925655E

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