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Issue 11, 2010
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Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system†

Stéphanie Boissé,ab   Jutta Rieger,*a   Khaled Belal,a   Aurélie Di-Cicco,b   Patricia Beaunier,c   Min-Hui Lib  and  Bernadette Charleux*ad  
Author affiliations

* Corresponding authors

a UPMC Univ. Paris 6 and CNRS, Laboratoire de Chimie des Polymères, UMR 7610, 4 place Jussieu, Tour 44-54, 75252 Paris cedex 05, France
E-mail: jutta.rieger@upmc.fr
Fax: +33 1 44277089
Tel: +33 1 44275137

b Institut Curie, CNRS, UPMC, Laboratoire Physico-Chimie Curie, UMR 168, 26 rue d’Ulm, 75248 Paris cedex 05, France

c UPMC Univ. Paris 6 and CNRS, Laboratoire de Réactivité de Surface, UMR 7197, 4 place Jussieu, 75252 Paris cedex 05, France

d Université de Lyon, Univ. Lyon 1, CPE Lyon, CNRS UMR 5265, C2P2, Team LCPP Bat 308F, 43 Bd du 11 novembre 1918, 69616 Villeurbanne, France
E-mail: bernadette.charleux@lcpp.cpe.fr

Abstract

Self-assembled block copolymer nanofibers are attractive materials for multiple applications. We propose here a novel, very simple and straightforward method to prepare polymeric nanofibers at high solids contents directly in water. It is based on an aqueous emulsion polymerization process performed under living radical polymerization conditions, using the RAFT method.

Graphical abstract: Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system

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Article information

https://doi.org/10.1039/B923667H
Submitted
12 Nov 2009
Accepted
18 Dec 2009
First published
18 Jan 2010
Chem. Commun., 2010,46, 1950-1952
Article type
Communication
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Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system

S. Boissé, J. Rieger, K. Belal, A. Di-Cicco, P. Beaunier, M. Li and B. Charleux, Chem. Commun., 2010, 46, 1950
DOI: 10.1039/B923667H

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