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Issue 11, 2010
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Total synthesis of (±)-aspercyclide A and its C19 methyl ether

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Abstract

The total syntheses of (±)-aspercyclide A (1) and its C19 methyl ether (15a) featuring Heck–Mizoroki macrocyclisation to form the 11-membered (E)-styrenyl biaryl ether lactone core are described.

Graphical abstract: Total synthesis of (±)-aspercyclide A and its C19 methyl ether

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Article information


Submitted
11 Nov 2009
Accepted
14 Dec 2009
First published
23 Dec 2009

Chem. Commun., 2010,46, 1824-1826
Article type
Communication

Total synthesis of (±)-aspercyclide A and its C19 methyl ether

J. L. Carr, D. A. Offermann, M. D. Holdom, P. Dusart, A. J. P. White, A. J. Beavil, R. J. Leatherbarrow, S. D. Lindell, B. J. Sutton and A. C. Spivey, Chem. Commun., 2010, 46, 1824
DOI: 10.1039/B923528K

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