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Issue 2, 2010
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Stereoselective synthesis of trans-β-lactams by palladium-catalysed carbonylation of vinyl aziridines

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Abstract

The palladium-catalysed carbonylation of vinyl aziridines can give either the trans- or cis-β-lactam preferentially or even the δ-lactam simply by adjusting the reaction parameters ([Pd], [CO], temperature).

Graphical abstract: Stereoselective synthesis of trans-β-lactams by palladium-catalysed carbonylation of vinyl aziridines

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Article information


Submitted
05 Oct 2009
Accepted
13 Nov 2009
First published
27 Nov 2009

Chem. Commun., 2010,46, 267-269
Article type
Communication

Stereoselective synthesis of trans-β-lactams by palladium-catalysed carbonylation of vinyl aziridines

F. Fontana, G. C. Tron, N. Barbero, S. Ferrini, S. P. Thomas and V. K. Aggarwal, Chem. Commun., 2010, 46, 267
DOI: 10.1039/B920564K

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