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Issue 5, 2010
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A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

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Abstract

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)4(OMc)12 (OMc = CH2[double bond, length as m-dash]CH(CH3)COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

Graphical abstract: A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(iv) dicarboxylates

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Publication details

The article was received on 23 Jul 2009, accepted on 19 Nov 2009 and first published on 10 Dec 2009


Article type: Communication
DOI: 10.1039/B914919H
Chem. Commun., 2010,46, 767-769

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    A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

    V. Guillerm, S. Gross, C. Serre, T. Devic, M. Bauer and G. Férey, Chem. Commun., 2010, 46, 767
    DOI: 10.1039/B914919H

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