Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6]

Fuyu Zhuge; Biao Wu; Jin Yang; Christoph Janiak; Ning Tang; Xiao-Juan Yang

doi:10.1039/B914216A

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Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)₃][Fe(CN)₆]†

Fuyu Zhuge,^ad Biao Wu,*^ab Jin Yang,^b Christoph Janiak,^c Ning Tang^b and Xiao-Juan Yang*^ab

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* Corresponding authors

^a State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China
E-mail: wubiao@lzb.ac.cn, yangxj@lzb.ac.cn
Fax: +86 931 4968286

^b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

^c Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 21, D-79104 Freiburg, Germany

^d Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A second-sphere complex [Co(DABP)₃][Fe(CN)₆] (1) (DABP = 5,5′-diamino-2,2′-bipyridine) is constructed from [Co(DABP)₃]³⁺ and [Fe(CN)₆]³⁻ through charge-assisted N–H_(NH₂)⋯N_(CN) hydrogen bonds; hexagonal microrods of 1 are obtained via a facile self-assembly method in the presence of surfactant.

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Article information

DOI: https://doi.org/10.1039/B914216A
Article type: Communication
Submitted: 15 Jul 2009
Accepted: 23 Nov 2009
First published: 15 Dec 2009

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Chem. Commun., 2010,46, 1121-1123

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Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)₃][Fe(CN)₆]

F. Zhuge, B. Wu, J. Yang, C. Janiak, N. Tang and X. Yang, Chem. Commun., 2010, 46, 1121 DOI: 10.1039/B914216A

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