Issue 8, 2010
From the journal:

Analytical Methods

Electrochemical determination of nitrobenzene using bismuth-film modified carbon paste electrode in the presence of cetyltrimethylammonium bromide

Liqiang Luo,*a   Xia Wang,a   Yaping Ding,a   Qiuxia Li,a   Jianbo Jia*b  and  Dongmei Denga  

* Corresponding authors

a College of Sciences, Shanghai University, 99 Shangda Road, Shanghai, PR China
E-mail: luoliqw@yahoo.com.cn
Fax: +86 21 66132797
Tel: +86 21 66134734

b State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, PR China
E-mail: jbjia@ciac.jl.cn

Abstract

Electrochemical behavior of nitrobenzene (NB) at a bismuth-film modified carbon paste electrode (BiF/CPE) in the presence of cetyltrimethylammonium bromide (CTAB) was investigated by square wave voltammetry. The electrochemical response of NB was apparently improved by CTAB due to the enhanced accumulation of NB at the electrode surface. Operational parameters including the deposition potential and time of bismuth film, pH of solutions and concentration of CTAB were investigated and optimized. Under optimized conditions, the cathodic peak current was proportional to the concentration of NB in the range of 1.0 × 10−6 to 1.0 × 10−4 mol L−1 with the detection limit of 8.3 × 10−7 mol L−1. The proposed BiF/CPE revealed good stability and reproducibility for rapid, simple and sensitive analysis of NB.

Graphical abstract: Electrochemical determination of nitrobenzene using bismuth-film modified carbon paste electrode in the presence of cetyltrimethylammonium bromide

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Article information

DOI
https://doi.org/10.1039/C0AY00150C
Article type
Paper
Submitted
02 Mar 2010
Accepted
10 May 2010
First published
10 Jun 2010

Anal. Methods, 2010,2, 1095-1100

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Electrochemical determination of nitrobenzene using bismuth-film modified carbon paste electrode in the presence of cetyltrimethylammonium bromide

L. Luo, X. Wang, Y. Ding, Q. Li, J. Jia and D. Deng, Anal. Methods, 2010, 2, 1095 DOI: 10.1039/C0AY00150C

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