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Co-assembly of ditopic perylene bisimide and azobenzene-functionalized melamine occurs with an unconventional stoichiometric ratio, providing well-defined nanostructures with a helically-coiled architecture where perylene chromophores are packed in desirable J-type arrangements.

Graphical abstract: Unconventional hydrogen-bond-directed hierarchical co-assembly between perylene bisimide and azobenzene-functionalized melamine

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