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Abstract | Cited by

An asymmetric synthesis of (+)-castanospermine is presented in which enol ether metathesis–hydroboration/oxidation is used for stereoselective installation of the trans-transhydroxyl groups on the piperidine ring of the alkaloid.

Graphical abstract: Asymmetric synthesis of (+)-castanospermine through enol ether metathesis–hydroboration/oxidation

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