Issue 11, 2009
From the journal:

New Journal of Chemistry

Oxidative transformation of thiol groups to disulfide bonds in mesoporous silicas: a diagnostic reaction for probing distribution of organic functional groups†

Hsien-Ming Kao,*a   Po-Jui Chiu,a   Guang-Liang Jheng,a   Chia-Chun Kao,a   Chung-Ta Tsai,a   Shueh-Lin Yau,a   Hui-Hsu Gavin Tsai*a  and  Yi-Kang Choua  

* Corresponding authors

a Department of Chemistry, National Central University, Chung-Li, R.O.C
E-mail: hmkao@cc.ncu.edu.tw, hhtsai@cc.ncu.edu.tw
Fax: +886 3-4227664

Abstract

A novel reaction route for the oxidation of thiol groups to disulfide bonds in mesoporous silicas with the aid of Cu2+ adsorption is reported for the first time, and most importantly it can serve as a diagnostic reaction for probing the spatial proximity and distribution of organic functional groups.

Graphical abstract: Oxidative transformation of thiol groups to disulfide bonds in mesoporous silicas: a diagnostic reaction for probing distribution of organic functional groups

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Article information

DOI
https://doi.org/10.1039/B9NJ00389D
Article type
Letter
Submitted
05 Aug 2009
Accepted
08 Sep 2009
First published
18 Sep 2009

New J. Chem., 2009,33, 2199-2203

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Oxidative transformation of thiol groups to disulfide bonds in mesoporous silicas: a diagnostic reaction for probing distribution of organic functional groups

H. Kao, P. Chiu, G. Jheng, C. Kao, C. Tsai, S. Yau, H. G. Tsai and Y. Chou, New J. Chem., 2009, 33, 2199 DOI: 10.1039/B9NJ00389D

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