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Issue 25, 2009
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Enhanced H2adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

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Abstract

A porous coordination polymer containing zinc, 1,2,4-triazolate, and tetrafluoroterephthalate displays a high physisorptive hydrogen adsorption enthalpy of 8 kJ/mol, as a result of fluorine atoms exposed to the pore surface and the structure's small pore size.

Graphical abstract: Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

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Article information


Submitted
15 Jan 2009
Accepted
09 Mar 2009
First published
19 Mar 2009

J. Mater. Chem., 2009,19, 4307-4309
Article type
Communication

Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

Z. Hulvey, E. H. L. Falcao, J. Eckert and A. K. Cheetham, J. Mater. Chem., 2009, 19, 4307
DOI: 10.1039/B900879A

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