Issue 43, 2009
From the journal:

Dalton Transactions

Self-assembly of star-shaped heteropoly-15-palladate(II)†

Natalya V. Izarova,a   Rosa Ngo Biboum,b   Bineta Keita,b   Maria Mifsud,c   Isabel W. C. E. Arends,c   Geoffrey B. Jamesond  and  Ulrich Kortz*a  

* Corresponding authors

a Jacobs University, School of Engineering and Science, P.O. Box 750 561, Bremen, Germany
E-mail: u.kortz@jacobs-university.de
Fax: +49 0421 200 3229
Tel: +49 0421 200 3235

b Laboratoire de Chimie Physique, UMR 8000, CNRS, Equipe d'Electrochimie et Photoélectrochimie, Université Paris-Sud, Bâtiment 350, Orsay Cedex, France

c Laboratory for Biocatalysis and Organic Chemistry, Delft University of Technology, Julianalaan 136, Delft, BL, The Netherlands

d Centre for Structural Biology, Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand

Abstract

A novel heteropolyoxopalladate structural type has been discovered: the polyoxo-15-palladate(II) [Pd0.4Na0.6⊂Pd15P10O50H6.6]12− (Pd15) has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD, elemental analysis, IR, TGA, 31P NMR and electrochemistry; preliminary catalytic studies showed that Pd15 is active as a catalyst in alcohol oxidation by dioxygen.

Graphical abstract: Self-assembly of star-shaped heteropoly-15-palladate(II)

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Article information

DOI
https://doi.org/10.1039/B917079K
Article type
Communication
Submitted
16 Jun 2009
Accepted
24 Aug 2009
First published
02 Sep 2009

Dalton Trans., 2009, 9385-9387

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Self-assembly of star-shaped heteropoly-15-palladate(II)

N. V. Izarova, R. N. Biboum, B. Keita, M. Mifsud, I. W. C. E. Arends, G. B. Jameson and U. Kortz, Dalton Trans., 2009, 9385 DOI: 10.1039/B917079K

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