Issue 39, 2009

Intermediate spin ground state of an isosceles triangular [MnII3] complex

Abstract

[{Mn(tmeda)}3{GeSe3(OMe)}2] (1), synthesized by the reaction of [K4(H2O)3][Ge2Se6] with MnCl2·4H2O in MeOH–tmeda (tmeda = N,N,N′,N′-tetramethyl-1,2-diaminoethane), exhibits an isosceles triangular arrangement of Mn2+ ions that are antiferromagnetically coupled with an S = 3/2 ground state.

Graphical abstract: Intermediate spin ground state of an isosceles triangular [MnII3] complex

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr 2009
Accepted
04 Aug 2009
First published
20 Aug 2009

Dalton Trans., 2009, 8162-8164

Intermediate spin ground state of an isosceles triangular [MnII3] complex

S. Haddadpour, H. Niedermeyer, R. Clérac and S. Dehnen, Dalton Trans., 2009, 8162 DOI: 10.1039/B914674C

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