Thiolates vs. halides as π-donors: the redox-active alkyne complexes [M(SR)L(η-R′C
CR′)L′] {M = Mo or W, L = CO or P(OMe)3, L′ = η-C5H5 and Tp′}†
Abstract
The CR′)(η-C5H5)] (M =
CMe)(η-C5H5)]+ were detected by
CPh)Tp′
CPh)Tp′]z
CPh)Tp′
CPh)Tp′
CPh)Tp′]z