Synthesis and characterization of a monomeric octahedral C2-symmetric titanium complex bearing two 3,3′-diphenyl-2,2′-biphenol ligands

Carine Diebold; Pierre Mobian; Clarisse Huguenard; Lionel Allouche; Marc Henry

doi:10.1039/B912694P

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Synthesis and characterization of a monomeric octahedral C₂-symmetric titanium complex bearing two 3,3′-diphenyl-2,2′-biphenol ligands†

Carine Diebold,^a Pierre Mobian,^a Clarisse Huguenard,^a Lionel Allouche^b and Marc Henry*^a

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie moléculaire de l'Etat Solide, Université de Strasbourg, Strasbourg, France
E-mail: henry@chimie.u-strasbg.fr

^b Service de RMN, Institut de Chimie, Université de Strasbourg, Strasbourg, France
E-mail: allouche@chimie.u-strasbg.fr

Abstract

The 3,3′-diphenyl-2,2′-biphenol (dpbpolH₂) ligand is shown to react with Ti(OPrⁱ)₄ in a 2:1 ratio to yield a novel C₂-symmetric mononuclear octahedral Ti(IV) bis-biphenolate complex, cis-Ti(dpbpol)₂(HOPrⁱ)₂.

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Article information

DOI: https://doi.org/10.1039/B912694P
Article type: Communication
Submitted: 26 Jun 2009
Accepted: 23 Sep 2009
First published: 08 Oct 2009

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Dalton Trans., 2009, 10178-10180

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Synthesis and characterization of a monomeric octahedral C₂-symmetric titanium complex bearing two 3,3′-diphenyl-2,2′-biphenol ligands

C. Diebold, P. Mobian, C. Huguenard, L. Allouche and M. Henry, Dalton Trans., 2009, 10178 DOI: 10.1039/B912694P

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Dalton Transactions