Issue 31, 2009
From the journal:

Dalton Transactions

Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion†

Dong-Hoon Won,a   Motoki Toganoh,a   Hidemitsu Uno‡b  and  Hiroyuki Furuta*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, Japan
E-mail: hfuruta@cstf.kyushu-u.ac.jp
Fax: +81 92-802-2865
Tel: +81 92-802-2865

b Department of Molecular Science Integrated Center for Sciences, Ehime University, Bunkyo-cho 2-5, Matsuyama, Japan

Abstract

Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl−, Br−, and I− anions at the peripheral N–H, while deprotonation proceeds with F−, H2PO4−, and OH− in CH2Cl2 solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.

Graphical abstract: Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

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Article information

DOI
https://doi.org/10.1039/B906018A
Article type
Paper
Submitted
26 Mar 2009
Accepted
07 May 2009
First published
17 Jun 2009

Dalton Trans., 2009, 6151-6158

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Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

D. Won, M. Toganoh, H. Uno and H. Furuta, Dalton Trans., 2009, 6151 DOI: 10.1039/B906018A

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