Issue 26, 2009
From the journal:

Dalton Transactions

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)†

Hans J. Breunig,*a   Enno Lork,a   Ovidiu Moldovan,a   Ciprian I. Raţ,b   Uwe Rosenthalc  and  Cristian Silvestrub  

* Corresponding authors

a Institut für Anorganische und Physikalische Chemie, Universität Bremen, Postfach 330 440, Bremen, Germany
E-mail: hbreunig@uni-bremen.de
Fax: +49 421 218 4042
Tel: +49 421 218 2266

b Facultatea de Chimie si Inginerie Chimica Universitatea Babes-Bolyai Arany Janos 11, Cluj-Napoca, Romania

c Leibniz-Institut für Katalyse e.V., Universität Rostock, Albert-Einstein-Strasse 29a, Rostock, Germany

Abstract

The formation and crystal structure of [(Cp2Ti)2(SbR2)2] (1, R = Et), [(Cp2Ti)3(SbR)3Sb] [2, R = 2-(Me2NCH2)C6H4], and [(Cp2Ti)5(SbR)2Sb7] (3, R = Me3SiCH2) is reported.

Graphical abstract: Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

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Article information

DOI
https://doi.org/10.1039/B904846D
Article type
Communication
Submitted
10 Mar 2009
Accepted
01 May 2009
First published
13 May 2009

Dalton Trans., 2009, 5065-5067

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Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

H. J. Breunig, E. Lork, O. Moldovan, C. I. Raţ, U. Rosenthal and C. Silvestru, Dalton Trans., 2009, 5065 DOI: 10.1039/B904846D

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