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Issue 24, 2009
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Combining two non-innocent ligands in isomeric complexes [Pt(pap)mQn]0 (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone

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Abstract

Isomeric complexes of platinum, which contain two non-innocent ligands are reported. The built-in coordination asymmetry in the ligands makes it possible to separate two different positional isomers. Results from X-ray crystallography is used to invoke the popular structure oxidation state correlation in these complexes. The redox processes are discussed and interpreted with the help of UV-vis–NIR and EPR spectroelectrochemistry.

Graphical abstract: Combining two non-innocent ligands in isomeric complexes [Pt(pap)mQn]0 (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone

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Article information


Submitted
09 Feb 2009
Accepted
15 Apr 2009
First published
23 Apr 2009

Dalton Trans., 2009, 4653-4655
Article type
Communication

Combining two non-innocent ligands in isomeric complexes [Pt(pap)mQn]0 (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone

B. Sarkar, R. Hübner, R. Pattacini and I. Hartenbach, Dalton Trans., 2009, 4653
DOI: 10.1039/B902645B

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