Issue 26, 2009
From the journal:

Dalton Transactions

Manganese complexes of phosphino-μ-phosphido ligands†

Peter G. Edwards,*a   F. Ekkehardt Hahn,b   Matthieu Limon,a   Paul D. Newman,a   Benson M. Kariukia  and  Andreas Stascha  

* Corresponding authors

a School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, United Kingdom
E-mail: edwardspg@cardiff.ac.uk
Fax: 029 20874030
Tel: 029 20874083

b Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Wilhelm Klemm Strasse 8, Münster, Germany
E-mail: fehahn@uni-muenster.de

Abstract

The reaction of the manganese precursors [MnOTf(CO)3{1,2-(PH2)2C6H4}], 5, or [MnOTf(CO)3{1,2-(PH2)2C2H4}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.

Graphical abstract: Manganese complexes of phosphino-μ-phosphido ligands

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Article information

DOI
https://doi.org/10.1039/B822870A
Article type
Paper
Submitted
18 Dec 2008
Accepted
01 Apr 2009
First published
30 Apr 2009

Dalton Trans., 2009, 5115-5119

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Manganese complexes of phosphino-μ-phosphido ligands

P. G. Edwards, F. E. Hahn, M. Limon, P. D. Newman, B. M. Kariuki and A. Stasch, Dalton Trans., 2009, 5115 DOI: 10.1039/B822870A

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