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Issue 19, 2009
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Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

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Abstract

This perspective focuses on the aldehyde C–H activation promoted by late transition metals, including the chelation-assisted reactions. The mechanisms currently accepted for different metal complexes, the reactivity of acyl hydrido species formed, and the reactions promoted on further aldehyde when using excess reagent are discussed. Homogeneous catalytic aldehyde decarbonylation or dimerization reactions are also reviewed.

Graphical abstract: Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

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Publication details

The article was received on 02 Oct 2008, accepted on 08 Jan 2009 and first published on 12 Feb 2009


Article type: Perspective
DOI: 10.1039/B817263C
Dalton Trans., 2009, 3635-3645

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    Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

    M. A. Garralda, Dalton Trans., 2009, 3635
    DOI: 10.1039/B817263C

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