Metal-free dihydrogenactivation chemistry: structural and dynamic features of intramolecular P/B pairs†‡
Abstract
CH2 (R = CH3, Ph) yield the corresponding (mesityl)2P(μ-CHRCH2)B(C6F5)2 products 9a (R = CH3) and 9b (R = Ph) that show a weak intramolecular
CHSiMe3. Compound 9a reacts rapidly with