Issue 4, 2009
From the journal:

Dalton Transactions

Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T†

Israel Cano,a   M. Carmen Nicasio*a  and  Pedro J. Pérez*a  

* Corresponding authors

a Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Campus de El Carmen s/n, Universidad de Huelva, Huelva, Spain
E-mail: perez@dqcm.uhu.es, mcnica@dqcm.uhu.es
Fax: +34 959219942
Tel: +34 959219956

Abstract

The complex [Tpm*,BrCu(NCMe)]BF4 (Tpm*,Br = HC(3,5-Me2-4-Br-pyrazolyl)3) catalyses the aziridination of alkenes and the amidation of cyclic ethers with chloramine-T as the nitrene source and the ionic liquid [bmim]PF6 as the reaction medium (bmim = 1-n-butyl-3-methylimidazolium). High conversions have been obtained over several cycles of catalyst recovery and reuse.

Graphical abstract: Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

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Article information

DOI
https://doi.org/10.1039/B813469C
Article type
Paper
Submitted
04 Aug 2008
Accepted
14 Oct 2008
First published
28 Nov 2008

Dalton Trans., 2009, 730-734

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Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

I. Cano, M. C. Nicasio and P. J. Pérez, Dalton Trans., 2009, 730 DOI: 10.1039/B813469C

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