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Issue 5, 2009
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Magnetic metal–organic frameworks

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Abstract

The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the field of magnetic metal–organic frameworks, in particular those containing cobalt(II). We examine the diversity of magnetic exchange interactions between nearest-neighbour moment carriers, covering from dimers to oligomers and discuss their implications in infinite chains, layers and networks, having a variety of topologies. We progress to the different forms of short-range magnetic ordering, giving rise to single-molecule-magnets and single-chain-magnets, to long-range ordering of two- and three-dimensional networks (323 references).

Graphical abstract: Magnetic metal–organic frameworks

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Article information


Submitted
14 Nov 2008
First published
24 Feb 2009

Chem. Soc. Rev., 2009,38, 1353-1379
Article type
Critical Review

Magnetic metal–organic frameworks

M. Kurmoo, Chem. Soc. Rev., 2009, 38, 1353
DOI: 10.1039/B804757J

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