Issue 39, 2009
From the journal:

Physical Chemistry Chemical Physics

Identification of valence electronic states of aqueous acetic acid in acid–base equilibrium using site-selective X-ray emission spectroscopy†

Yuka Horikawa,ab   Takashi Tokushima,a   Yoshihisa Harada,acd   Osamu Takahashi,e   Ashish Chainani,a   Yasunori Senba,f   Haruhiko Ohashi,f   Atsunari Hirayab  and  Shik Shinag  

a RIKEN/SPring-8, Kouto, Sayo, Hyogo 679-5148, Japan

b Department of Physical Science, Hiroshima University, Higashi-Hiroshima, Hiroshima 739-8526, Japan

c Department of Applied Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan

d JST, CREST, Kawaguchi, Saitama 332-0012, Japan

e Department of Chemistry, Hiroshima University, Higashi-Hiroshima, Hiroshima 739-8526, Japan

f JASRI/SPring-8, KoutoSayo, Hyogo 679-5198, Japan

g Institute for Solid State Physics (ISSP), The University of Tokyo, Kashiwa, Chiba 277-8581, Japan

Abstract

Occupied valence electronic structures in the neutral and the anionic forms of aqueous acetic acid and their pH dependence under ambient condition are identified for the first time exploiting the site-selectivity of resonant X-ray emission spectroscopy (XES) in combination with calculation based on density functional theory (DFT).

Graphical abstract: Identification of valence electronic states of aqueous acetic acid in acid–base equilibrium using site-selective X-ray emission spectroscopy

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Article information

DOI
https://doi.org/10.1039/B910039C
Article type
Communication
Submitted
09 Jun 2009
Accepted
06 Jul 2009
First published
22 Jul 2009

Phys. Chem. Chem. Phys., 2009,11, 8676-8679

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Identification of valence electronic states of aqueous acetic acid in acid–base equilibrium using site-selective X-ray emission spectroscopy

Y. Horikawa, T. Tokushima, Y. Harada, O. Takahashi, A. Chainani, Y. Senba, H. Ohashi, A. Hiraya and S. Shin, Phys. Chem. Chem. Phys., 2009, 11, 8676 DOI: 10.1039/B910039C

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