Issue 26, 2009
From the journal:

Physical Chemistry Chemical Physics

IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings†

Gérald Chaplais,*a   Angélique Simon-Masseron,a   Florence Porcher,*bc   Claude Lecomte,c   Delphine Bazer-Bachi,d   Nicolas Batsd  and  Joël Patarina  

* Corresponding authors

a Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), LRC CNRS 7228, Université Haute Alsace, ENSCMu, 3 rue Alfred Werner, Mulhouse Cedex, France
E-mail: gerald.chaplais@uha.fr
Fax: +33 3 89 33 68 85
Tel: +33 3 89 33 68 87

b CEA, IRAMIS, Laboratoire Léon Brillouin, 91191 Gif sur Yvette, France. LLB, UMR 12 CEA-CNRS, Gif sur Yvette, France
E-mail: Florence.Porcher@cea.fr
Fax: +33 1 69 08 82 61
Tel: +33 1 69 08 49 54

c Cristallographie, Résonance Magnétique et Modélisations (CRM2), UMR 7036 CNRS-Université Henri Poincaré Nancy 1, Boulevard des Aiguillettes, BP 239, Vandoeuvre-lès-Nancy, France

d IFP-Lyon, BP 3, Solaize, France

Abstract

Five metal–organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.

Graphical abstract: IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

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Article information

DOI
https://doi.org/10.1039/B822163D
Article type
Communication
Submitted
11 Dec 2008
Accepted
01 Apr 2009
First published
24 Apr 2009

Phys. Chem. Chem. Phys., 2009,11, 5241-5245

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IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

G. Chaplais, A. Simon-Masseron, F. Porcher, C. Lecomte, D. Bazer-Bachi, N. Bats and J. Patarin, Phys. Chem. Chem. Phys., 2009, 11, 5241 DOI: 10.1039/B822163D

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