Issue 20, 2009
From the journal:

Physical Chemistry Chemical Physics

Supramolecular self-assembled multilayers of terpyridine-functionalized perylene bisimide metal complexes†

N. Tuccitto,a   I. Delfanti,a   V. Torrisi,a   F. Scandola,*b   C. Chiorboli,b   V. Stepanenko,c   F. Würthner*c  and  A. Licciardello*a  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università degli Studi di Catania, Via A. Doria 6, Catania, Italy
E-mail: alicciardello@unict.it
Fax: +39 095 580138
Tel: +39 095 7385086

b Dipartimento di Chimica, Università di Ferrara, Via L. Borsari 46, Ferrara, Italy
E-mail: scn@unife.it
Fax: +39 0532 240709
Tel: +39 0532 455160

c Universität Würzburg, Institut für Organische Chemie, Am Hubland, Würzburg, Germany
E-mail: wuerthner@chemie.uni-wuerzburg.de
Fax: +49 931 888 4756
Tel: +49 931 888 5340

Abstract

A terpyridine-functionalized perylene bisimide chromophore (TPBI) has been used as a building block in the stepwise, layer-by-layer fabrication of self-assembled Fe–TPBI multilayers on gold, with the assembled supramolecular chains oriented approximately perpendicular to the gold surface. Time-resolved spectroscopy measurements seem to indicate that the energy absorbed by the multilayer is promptly dissipated to the gold surface by ultrafast processes.

Graphical abstract: Supramolecular self-assembled multilayers of terpyridine-functionalized perylene bisimide metal complexes

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Article information

DOI
https://doi.org/10.1039/B819711N
Article type
Paper
Submitted
04 Nov 2008
Accepted
12 Feb 2009
First published
25 Mar 2009

Phys. Chem. Chem. Phys., 2009,11, 4033-4038

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Supramolecular self-assembled multilayers of terpyridine-functionalized perylene bisimide metal complexes

N. Tuccitto, I. Delfanti, V. Torrisi, F. Scandola, C. Chiorboli, V. Stepanenko, F. Würthner and A. Licciardello, Phys. Chem. Chem. Phys., 2009, 11, 4033 DOI: 10.1039/B819711N

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