Systematic variation of the substitution pattern of 2-pyridin-2-yl-1,10-phenanthrolines with 4-methoxy-2,6-dimethylphenyl (manisyl) groups α, β, and γ to the nitrogen atoms results in a 3 × 3 array of pyridyl-phenanthrolines displaying low to high quantum yields (Φf = 0.03–0.60). Photophysical studies elucidated a duality of emissive states: a weakly emissive, locally excited state, similar to the 1π,π* state of phenanthroline; and a strongly emissive, charge-transfer state, dependent on manisyl regiochemistry and solvent polarity. Ab initio calculations underscore the similarities in the electronic structures of phenanthroline and pyridyl-phenanthrolines rather than between terpyridine and pyridyl-phenanthroline.
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