Solid state crystal-to-crystal transformation from a monomeric structure to 1-D coordination polymers on anion exchange,

Mojtaba Khanpour; Ali Morsali

doi:10.1039/B908362F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Solid state crystal-to-crystal transformation from a monomeric structure to 1-D coordination polymers on anion exchange†^,‡

Mojtaba Khanpour^a and Ali Morsali*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Islamic Republic of Iran

Abstract

Yellow crystals of monomeric structure [Zn(bpdh)₂(H₂O)₄](NO₃)₂·2bpdh (1) convert on heating at ca. 160 °C under grinding and mixing with KSCN or NaN₃ to white and orange 1D coordination polymers, [Zn(µ-bpdh)₂(NCS)₂]_n (2) and [Zn(µ-bpdh)₂(N₃)₂]_n (3), respectively. In the crystal lattice, the coordination number of Zn(II) does not change with the removal of four water molecules and forms a new type of Zn⋯N_bpdh and Zn⋯N_NCS/N3.

This article is part of the themed collection: Editor’s Collection: Mechanochemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B908362F
Article type: Communication
Submitted: 27 Apr 2009
Accepted: 29 Jul 2009
First published: 21 Aug 2009

Download Citation

CrystEngComm, 2009,11, 2585-2587

Permissions

Request permissions

Solid state crystal-to-crystal transformation from a monomeric structure to 1-D coordination polymers on anion exchange^,

M. Khanpour and A. Morsali, CrystEngComm, 2009, 11, 2585 DOI: 10.1039/B908362F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm