Co-crystallisation of thiazyl radicals: preparation and crystal structure of [PhCNSSN][C6F5CNSSN]

Charlotte Allen; Delia A. Haynes; Christopher M. Pask; Jeremy M. Rawson

doi:10.1039/B906225D

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Co-crystallisation of thiazyl radicals: preparation and crystal structure of [PhCNSSN][C₆F₅CNSSN]†

Charlotte Allen,^a Delia A. Haynes,*^b Christopher M. Pask^a and Jeremy M. Rawson*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: jmr31@cam.ac.uk

^b Department of Chemistry and Polymer Science, Stellenbosch University, P. Bag X1, Matieland, Republic of South Africa
E-mail: dhaynes@sun.ac.za

Abstract

Co-sublimation of the two dithiadiazolyl radicals [PhCNSSN]₂ (1)₂ and [C₆F₅CNSSN]₂ (2)₂ yielded the mixed π*–π* dimer [PhCNSSN][C₆F₅CNSSN] (3) exhibiting aryl–perfluoroaryl π–π interactions.

This article is part of the themed collection: Crystal engineering in molecular magnetism

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Article information

DOI: https://doi.org/10.1039/B906225D
Article type: Communication
Submitted: 30 Mar 2009
Accepted: 28 May 2009
First published: 12 Jun 2009

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CrystEngComm, 2009,11, 2048-2050

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Co-crystallisation of thiazyl radicals: preparation and crystal structure of [PhCNSSN][C₆F₅CNSSN]

C. Allen, D. A. Haynes, C. M. Pask and J. M. Rawson, CrystEngComm, 2009, 11, 2048 DOI: 10.1039/B906225D

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