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Issue 4, 2009
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m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

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Abstract

A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation of either 1 or 2.

Graphical abstract: m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

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Publication details

The article was received on 15 Sep 2008, accepted on 02 Dec 2008 and first published on 07 Jan 2009


Article type: Communication
DOI: 10.1039/B816132C
CrystEngComm, 2009,11, 556-559

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    m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

    J. Rueff, V. Caignaert, A. Leclaire, C. Simon, J. Haelters and P. Jaffrès, CrystEngComm, 2009, 11, 556
    DOI: 10.1039/B816132C

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