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Issue 2, 2009
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Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(ii)-azide-pyrazine (6,3) 2D net

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Abstract

The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-µ-1,1azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.

Graphical abstract: Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(ii)-azide-pyrazine (6,3) 2D net

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Article information


Submitted
02 Sep 2008
Accepted
23 Oct 2008
First published
17 Nov 2008

CrystEngComm, 2009,11, 223-225
Article type
Communication

Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net

A. A. Massoud, M. A. M. Abu-Youssef, J. P. Vejpravová, V. Langer and L. Öhrström, CrystEngComm, 2009, 11, 223
DOI: 10.1039/B815264K

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