Issue 2, 2009
From the journal:

CrystEngComm

Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(ii)-azide-pyrazine (6,3) 2D net†

Alshima'a A. Massoud,*ab   Morsy A. M. Abu-Youssef,b   Jana Poltierová Vejpravová,c   Vratislav Langera  and  Lars Öhrström*a  

* Corresponding authors

a Department of Chemical and Biological Engineering, Chalmers University of Technology, Göteborg, Sweden
E-mail: langer@chalmers.se, ohrstrom@chalmers.se, shimo@chalmers.se
Fax: +46 31 772 3858
Tel: +46 31 772 1000

b Chemistry Department, Faculty of Science, Alexandria University, P.O. Box 426, Ibrahimia, Alexandria, Egypt
E-mail: morsy5@link.net
Fax: +2 03 5932488
Tel: +2 03 5917883

c Charles University, Faculty of Mathematics and Physics, DCMP, Ke Karlovu 5, Praha 2, Czech Republic
E-mail: jana@mag.mff.cuni.cz
Tel: +420-2-21911655

Abstract

The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-µ-1,1azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.

Graphical abstract: Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(ii)-azide-pyrazine (6,3) 2D net

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Article information

DOI
https://doi.org/10.1039/B815264K
Article type
Communication
Submitted
02 Sep 2008
Accepted
23 Oct 2008
First published
17 Nov 2008

CrystEngComm, 2009,11, 223-225

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Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net

A. A. Massoud, M. A. M. Abu-Youssef, J. P. Vejpravová, V. Langer and L. Öhrström, CrystEngComm, 2009, 11, 223 DOI: 10.1039/B815264K

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