Issue 45, 2009
From the journal:

Chemical Communications

Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2]†

Holger Braunschweig,*a   Qing Yea  and  Krzystof Radackia  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 888 4623
Tel: +49 931 31 85260

Abstract

Photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2] to the platinum σ-alkynyl complex [Cl(PMe3)2Pt–C[triple bond, length as m-dash]CPh] gave facile access to the first transition metal–borirene complex. The title compound has been fully characterized in solution and by X-ray crystallography.

Graphical abstract: Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr [[double bond, length as m-dash]] BN(SiMe3)2]

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Article information

DOI
https://doi.org/10.1039/B915926F
Article type
Communication
Submitted
04 Aug 2009
Accepted
05 Oct 2009
First published
15 Oct 2009

Chem. Commun., 2009, 6979-6981

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Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2]

H. Braunschweig, Q. Ye and K. Radacki, Chem. Commun., 2009, 6979 DOI: 10.1039/B915926F

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