Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product

Juri Ugolotti; Gerald Kehr; Roland Fröhlich; Stefan Grimme; Gerhard Erker

doi:10.1039/B915924J

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Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product†

Juri Ugolotti,^a Gerald Kehr,^a Roland Fröhlich,‡^a Stefan Grimme §^a and Gerhard Erker*^a

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* Corresponding authors

^a Organisch-Chemisches Institut der Universität, Corrensstrasse 40, Münster, Germany
E-mail: erker@uni-muenster.de
Fax: +49 251 8336503
Tel: +49 251 8333221

Abstract

Nitrile insertion into a zirconacycloallenoid complex leads to the formation of a seven-membered ring product with an attached boratirane unit.

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Article information

DOI: https://doi.org/10.1039/B915924J
Article type: Communication
Submitted: 04 Aug 2009
Accepted: 22 Sep 2009
First published: 07 Oct 2009

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Chem. Commun., 2009, 6572-6573

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Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product

J. Ugolotti, G. Kehr, R. Fröhlich, S. Grimme and G. Erker, Chem. Commun., 2009, 6572 DOI: 10.1039/B915924J

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Chemical Communications

Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product†

Abstract

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Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product

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