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We have prepared complexes of formula [Eu(β-diketonate)3(DPEPO)] and shown quantitative excited-state energy transfer from the ligands combined with efficient Ln luminescence leading to exceptionally-high total photoluminescence quantum yield of up to 80% in solution and in PMMA.

Graphical abstract: Europium complexes with high total photoluminescence quantum yields in solution and in PMMA

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